{"id":2039,"date":"2025-02-14T17:14:15","date_gmt":"2025-02-14T09:14:15","guid":{"rendered":"\/\/www.weareuncalledfor.com\/archives\/2039"},"modified":"2025-02-14T17:14:15","modified_gmt":"2025-02-14T09:14:15","slug":"%e7%83%ad%e6%95%8f%e5%bb%b6%e8%bf%9f%e5%82%ac%e5%8c%96%e5%89%82%e6%bb%a1%e8%b6%b3%e4%b8%a5%e6%a0%bc%e7%8e%af%e4%bf%9d%e6%a0%87%e5%87%86%e7%9a%84%e6%96%b0%e6%96%b9%e6%b3%95%e6%8e%a2%e7%b4%a2","status":"publish","type":"post","link":"\/\/www.weareuncalledfor.com\/archives\/2039","title":{"rendered":"\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u6ee1\u8db3\u4e25\u683c\u73af\u4fdd\u6807\u51c6\u7684\u65b0\u65b9\u6cd5\u63a2\u7d22"},"content":{"rendered":"<h3>\u5f15\u8a00<\/h3>\n<p>\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08Thermally Sensitive Delayed Catalyst, TSDC\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u5316\u5b66\u53cd\u5e94\u8c03\u63a7\u5de5\u5177\uff0c\u5728\u73b0\u4ee3\u5316\u5de5\u3001\u6750\u6599\u79d1\u5b66\u548c\u533b\u836f\u9886\u57df\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u4f20\u7edf\u7684\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u5f80\u5f80\u8868\u73b0\u51fa\u8fc7\u9ad8\u7684\u6d3b\u6027\uff0c\u5bfc\u81f4\u53cd\u5e94\u901f\u7387\u96be\u4ee5\u63a7\u5236\uff0c\u8fdb\u800c\u5f71\u54cd\u4ea7\u54c1\u8d28\u91cf\u548c\u751f\u4ea7\u6548\u7387\u3002\u800cTSDC\u80fd\u591f\u5728\u7279\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u8f83\u4f4e\u7684\u6d3b\u6027\uff0c\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\u9010\u6e10\u91ca\u653e\u50ac\u5316\u6d3b\u6027\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u53cd\u5e94\u8fc7\u7a0b\u7684\u7cbe\u786e\u63a7\u5236\u3002\u8fd9\u79cd\u7279\u6027\u4f7f\u5f97TSDC\u5728\u7cbe\u7ec6\u5316\u5de5\u3001\u805a\u5408\u7269\u5408\u6210\u3001\u836f\u7269\u5236\u9020\u7b49\u9886\u57df\u5177\u6709\u663e\u8457\u7684\u4f18\u52bf\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u5168\u7403\u73af\u4fdd\u610f\u8bc6\u7684\u589e\u5f3a\u548c\u5404\u56fd\u653f\u5e9c\u5bf9\u73af\u5883\u4fdd\u62a4\u7684\u91cd\u89c6\uff0c\u4fc3\u4f7f\u5de5\u4e1a\u754c\u4e0d\u65ad\u5bfb\u6c42\u66f4\u52a0\u73af\u4fdd\u3001\u9ad8\u6548\u7684\u751f\u4ea7\u5de5\u827a\u3002\u4f20\u7edf\u7684\u50ac\u5316\u5242\u548c\u5de5\u827a\u5f80\u5f80\u4f34\u968f\u7740\u5927\u91cf\u7684\u526f\u4ea7\u7269\u3001\u5e9f\u6c14\u6392\u653e\u548c\u80fd\u6e90\u6d88\u8017\uff0c\u4e0d\u7b26\u5408\u73b0\u4ee3\u7eff\u8272\u5316\u5b66\u7684\u8981\u6c42\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u6ee1\u8db3\u4e25\u683c\u73af\u4fdd\u6807\u51c6\u7684\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u6210\u4e3a\u4e86\u4e00\u4e2a\u91cd\u8981\u7684\u7814\u7a76\u65b9\u5411\u3002\u672c\u6587\u5c06\u63a2\u8ba8\u5982\u4f55\u901a\u8fc7\u521b\u65b0\u7684\u65b9\u6cd5\u548c\u6280\u672f\uff0c\u8bbe\u8ba1\u548c\u5236\u5907\u7b26\u5408\u73af\u4fdd\u8981\u6c42\u7684TSDC\uff0c\u5e76\u5bf9\u5176\u6027\u80fd\u8fdb\u884c\u7cfb\u7edf\u8bc4\u4ef7\uff0c\u4e3a\u76f8\u5173\u9886\u57df\u7684\u5e94\u7528\u63d0\u4f9b\u7406\u8bba\u4f9d\u636e\u548c\u6280\u672f\u652f\u6301\u3002<\/p>\n<p>\u5728\u63a5\u4e0b\u6765\u7684\u7ae0\u8282\u4e2d\uff0c\u6211\u4eec\u5c06\u9996\u5148\u56de\u987e\u73b0\u6709\u7684TSDC\u7814\u7a76\u8fdb\u5c55\uff0c\u5206\u6790\u5176\u4f18\u7f3a\u70b9\uff1b\u7136\u540e\u8be6\u7ec6\u4ecb\u7ecd\u4e00\u79cd\u57fa\u4e8e\u65b0\u578b\u6750\u6599\u548c\u5de5\u827a\u7684TSDC\u8bbe\u8ba1\u65b9\u6cd5\uff0c\u5305\u62ec\u5176\u5236\u5907\u8fc7\u7a0b\u3001\u7ed3\u6784\u7279\u5f81\u548c\u6027\u80fd\u53c2\u6570\uff1b\u63a5\u7740\u63a2\u8ba8\u8be5\u50ac\u5316\u5242\u5728\u4e0d\u540c\u5e94\u7528\u573a\u666f\u4e2d\u7684\u8868\u73b0\u53ca\u5176\u73af\u5883\u53cb\u597d\u6027\uff1b\u540e\u603b\u7ed3\u5168\u6587\uff0c\u5e76\u5c55\u671b\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u548c\u53d1\u5c55\u8d8b\u52bf\u3002<\/p>\n<h3>\u73b0\u6709\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u7684\u7814\u7a76\u8fdb\u5c55<\/h3>\n<p>\u8fd1\u5e74\u6765\uff0c\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TSDC\uff09\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\uff0c\u5c24\u5176\u662f\u5728\u6750\u6599\u9009\u62e9\u3001\u5236\u5907\u5de5\u827a\u548c\u5e94\u7528\u9886\u57df\u65b9\u9762\u3002\u6839\u636e\u4e0d\u540c\u7684\u50ac\u5316\u673a\u5236\u548c\u6750\u6599\u7279\u6027\uff0cTSDC\u53ef\u4ee5\u5206\u4e3a\u6709\u673a\u7c7b\u3001\u65e0\u673a\u7c7b\u548c\u590d\u5408\u7c7b\u4e09\u7c7b\u3002\u4ee5\u4e0b\u662f\u5404\u7c7bTSDC\u7684\u4e3b\u8981\u7814\u7a76\u6210\u679c\u53ca\u5176\u4f18\u7f3a\u70b9\u5206\u6790\u3002<\/p>\n<h4>1. \u6709\u673a\u7c7b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p>\u6709\u673a\u7c7bTSDC\u4e3b\u8981\u7531\u6709\u673a\u5316\u5408\u7269\u6216\u805a\u5408\u7269\u7ec4\u6210\uff0c\u5e38\u89c1\u7684\u6709\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u3001\u5171\u4ef7\u6709\u673a\u6846\u67b6\uff08COFs\uff09\u4ee5\u53ca\u529f\u80fd\u6027\u805a\u5408\u7269\u7b49\u3002\u8fd9\u7c7b\u50ac\u5316\u5242\u7684\u4f18\u70b9\u5728\u4e8e\u5176\u7ed3\u6784\u53ef\u8c03\u6027\u5f3a\uff0c\u53ef\u4ee5\u901a\u8fc7\u6539\u53d8\u5206\u5b50\u7ed3\u6784\u6765\u8c03\u8282\u50ac\u5316\u6d3b\u6027\u548c\u70ed\u654f\u6027\u3002\u4f8b\u5982\uff0cMOFs\u7531\u4e8e\u5176\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u53ef\u8c03\u63a7\u7684\u5b54\u9053\u7ed3\u6784\uff0c\u80fd\u591f\u6709\u6548\u5730\u8d1f\u8f7d\u6d3b\u6027\u91d1\u5c5e\u79bb\u5b50\u6216\u5206\u5b50\uff0c\u4ece\u800c\u5b9e\u73b0\u5bf9\u53cd\u5e94\u7684\u7cbe\u51c6\u63a7\u5236\u3002\u6b64\u5916\uff0cCOFs\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\uff0c\u9002\u7528\u4e8e\u9ad8\u6e29\u6761\u4ef6\u4e0b\u7684\u50ac\u5316\u53cd\u5e94\u3002<\/p>\n<p>\u7136\u800c\uff0c\u6709\u673a\u7c7bTSDC\u4e5f\u5b58\u5728\u4e00\u4e9b\u5c40\u9650\u6027\u3002\u9996\u5148\uff0c\u6709\u673a\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027\u8f83\u5dee\uff0c\u5bb9\u6613\u5728\u9ad8\u6e29\u4e0b\u5206\u89e3\u6216\u5931\u6d3b\uff0c\u9650\u5236\u4e86\u5176\u5728\u9ad8\u6e29\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u3002\u5176\u6b21\uff0c\u6709\u673a\u50ac\u5316\u5242\u7684\u5236\u5907\u8fc7\u7a0b\u901a\u5e38\u8f83\u4e3a\u590d\u6742\uff0c\u6d89\u53ca\u5230\u591a\u6b65\u5408\u6210\u548c\u540e\u5904\u7406\uff0c\u6210\u672c\u8f83\u9ad8\u3002\u6b64\u5916\uff0c\u67d0\u4e9b\u6709\u673a\u5316\u5408\u7269\u53ef\u80fd\u5177\u6709\u4e00\u5b9a\u7684\u6bd2\u6027\u6216\u73af\u5883\u5371\u5bb3\uff0c\u4e0d\u7b26\u5408\u4e25\u683c\u7684\u73af\u4fdd\u6807\u51c6\u3002<\/p>\n<h4>2. \u65e0\u673a\u7c7b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p>\u65e0\u673a\u7c7bTSDC\u4e3b\u8981\u5305\u62ec\u91d1\u5c5e\u6c27\u5316\u7269\u3001\u786b\u5316\u7269\u3001\u6c2e\u5316\u7269\u7b49\u56fa\u4f53\u6750\u6599\u3002\u8fd9\u4e9b\u6750\u6599\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u80fd\u591f\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u6d3b\u6027\u3002\u4f8b\u5982\uff0c\u4e8c\u6c27\u5316\u949b\uff08TiO\u2082\uff09\u662f\u4e00\u79cd\u5e38\u89c1\u7684\u5149\u50ac\u5316\u5242\uff0c\u7ecf\u8fc7\u6539\u6027\u540e\u53ef\u4ee5\u4f5c\u4e3aTSDC\u4f7f\u7528\uff0c\u5176\u5728\u53ef\u89c1\u5149\u7167\u5c04\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u6b64\u5916\uff0c\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u5982\u6c27\u5316\u94c1\uff08Fe\u2082O\u2083\uff09\u3001\u6c27\u5316\u9530\uff08MnO\u2082\uff09\u7b49\u4e5f\u56e0\u5176\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u50ac\u5316\u6d3b\u6027\u800c\u88ab\u5e7f\u6cdb\u7814\u7a76\u3002<\/p>\n<p>\u5c3d\u7ba1\u65e0\u673a\u7c7bTSDC\u5177\u6709\u8f83\u597d\u7684\u7a33\u5b9a\u6027\u548c\u8010\u4e45\u6027\uff0c\u4f46\u5b83\u4eec\u7684\u50ac\u5316\u6d3b\u6027\u76f8\u5bf9\u8f83\u5f31\uff0c\u5c24\u5176\u662f\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u53cd\u5e94\u901f\u7387\u8f83\u4f4e\u3002\u6b64\u5916\uff0c\u65e0\u673a\u6750\u6599\u7684\u6bd4\u8868\u9762\u79ef\u8f83\u5c0f\uff0c\u9650\u5236\u4e86\u5176\u4e0e\u53cd\u5e94\u7269\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u5f71\u54cd\u4e86\u50ac\u5316\u6548\u7387\u3002\u4e3a\u4e86\u63d0\u9ad8\u65e0\u673a\u50ac\u5316\u5242\u7684\u6027\u80fd\uff0c\u7814\u7a76\u4eba\u5458\u901a\u5e38\u91c7\u7528\u7eb3\u7c73\u5316\u3001\u63ba\u6742\u6216\u590d\u5408\u7b49\u624b\u6bb5\uff0c\u4f46\u8fd9\u4e5f\u4f1a\u589e\u52a0\u5236\u5907\u96be\u5ea6\u548c\u6210\u672c\u3002<\/p>\n<h4>3. \u590d\u5408\u7c7b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242<\/h4>\n<p>\u590d\u5408\u7c7bTSDC\u7ed3\u5408\u4e86\u6709\u673a\u548c\u65e0\u673a\u6750\u6599\u7684\u4f18\u70b9\uff0c\u901a\u8fc7\u5c06\u4e24\u8005\u590d\u5408\u5728\u4e00\u8d77\uff0c\u5f62\u6210\u5177\u6709\u534f\u540c\u6548\u5e94\u7684\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u4f8b\u5982\uff0c\u5c06\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u5728\u6709\u673a\u805a\u5408\u7269\u6216\u78b3\u57fa\u6750\u6599\u4e0a\uff0c\u53ef\u4ee5\u540c\u65f6\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u3002\u590d\u5408\u7c7bTSDC\u8fd8\u53ef\u4ee5\u901a\u8fc7\u5f15\u5165\u529f\u80fd\u5316\u57fa\u56e2\u6216\u8868\u9762\u4fee\u9970\uff0c\u8fdb\u4e00\u6b65\u589e\u5f3a\u5176\u9009\u62e9\u6027\u548c\u6297\u4e2d\u6bd2\u80fd\u529b\u3002<\/p>\n<p>\u590d\u5408\u7c7bTSDC\u7684\u4e3b\u8981\u4f18\u52bf\u5728\u4e8e\u5176\u591a\u529f\u80fd\u6027\u548c\u7075\u6d3b\u6027\uff0c\u53ef\u4ee5\u6839\u636e\u5177\u4f53\u5e94\u7528\u9700\u6c42\u8fdb\u884c\u5b9a\u5236\u8bbe\u8ba1\u3002\u7136\u800c\uff0c\u590d\u5408\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u8f83\u4e3a\u590d\u6742\uff0c\u6d89\u53ca\u5230\u591a\u79cd\u6750\u6599\u7684\u5408\u6210\u548c\u7ec4\u88c5\uff0c\u4e14\u4e0d\u540c\u7ec4\u5206\u4e4b\u95f4\u7684\u76f8\u5bb9\u6027\u548c\u754c\u9762\u6548\u5e94\u9700\u8981\u4ed4\u7ec6\u4f18\u5316\u3002\u6b64\u5916\uff0c\u590d\u5408\u6750\u6599\u7684\u6210\u672c\u8f83\u9ad8\uff0c\u5c24\u5176\u662f\u5f53\u4f7f\u7528\u8d35\u91d1\u5c5e\u6216\u7a00\u6709\u5143\u7d20\u65f6\uff0c\u7ecf\u6d4e\u6027\u95ee\u9898\u4e0d\u5bb9\u5ffd\u89c6\u3002<\/p>\n<h4>\u56fd\u5185\u5916\u6587\u732e\u7efc\u8ff0<\/h4>\n<p>\u56fd\u5185\u5916\u5b66\u8005\u5728TSDC\u9886\u57df\u8fdb\u884c\u4e86\u5927\u91cf\u7814\u7a76\uff0c\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u91cd\u8981\u6210\u679c\u3002\u56fd\u5916\u6587\u732e\u4e2d\uff0c\u7f8e\u56fd\u5316\u5b66\u5b66\u4f1a\uff08ACS\uff09\u671f\u520a\u300aJournal of the American Chemical Society\u300b\u548c\u300aACS Catalysis\u300b\u53d1\u8868\u4e86\u591a\u7bc7\u5173\u4e8eMOFs\u548cCOFs\u5728TSDC\u4e2d\u7684\u5e94\u7528\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u8fd9\u4e9b\u6750\u6599\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u72ec\u7279\u4f18\u52bf\u3002\u5fb7\u56fd\u300aAngewandte Chemie International Edition\u300b\u6742\u5fd7\u5219\u62a5\u9053\u4e86\u5229\u7528\u7eb3\u7c73\u6280\u672f\u6539\u8fdb\u65e0\u673a\u50ac\u5316\u5242\u6027\u80fd\u7684\u5de5\u4f5c\uff0c\u5c55\u793a\u4e86\u7eb3\u7c73\u6750\u6599\u5728\u63d0\u9ad8\u50ac\u5316\u6548\u7387\u65b9\u9762\u7684\u6f5c\u529b\u3002<\/p>\n<p>\u56fd\u5185\u65b9\u9762\uff0c\u6e05\u534e\u5927\u5b66\u3001\u5317\u4eac\u5927\u5b66\u3001\u4e2d\u79d1\u9662\u7b49\u9ad8\u6821\u548c\u7814\u7a76\u673a\u6784\u5728TSDC\u9886\u57df\u4e5f\u5f00\u5c55\u4e86\u6df1\u5165\u7814\u7a76\u3002\u4f8b\u5982\uff0c\u6e05\u534e\u5927\u5b66\u5316\u5b66\u7cfb\u7684\u7814\u7a76\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u57fa\u4e8e\u77f3\u58a8\u70ef\u548c\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u590d\u5408\u50ac\u5316\u5242\uff0c\u6210\u529f\u5e94\u7528\u4e8e\u805a\u5408\u7269\u5408\u6210\u4e2d\uff0c\u663e\u8457\u63d0\u9ad8\u4e86\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u4ea7\u7387\u3002\u590d\u65e6\u5927\u5b66\u7684\u7814\u7a76\u4eba\u5458\u5219\u901a\u8fc7\u5f15\u5165\u7a00\u571f\u5143\u7d20\u6539\u6027\u6c27\u5316\u7269\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u4e86\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u7cbe\u786e\u8c03\u63a7\uff0c\u4e3aTSDC\u7684\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n<p>\u603b\u7684\u6765\u8bf4\uff0c\u73b0\u6709TSDC\u7684\u7814\u7a76\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u8fdb\u5c55\uff0c\u4f46\u5728\u73af\u4fdd\u6027\u80fd\u3001\u50ac\u5316\u6548\u7387\u548c\u6210\u672c\u63a7\u5236\u7b49\u65b9\u9762\u4ecd\u9762\u4e34\u6311\u6218\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u65b0\u578b\u7684\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff0c\u7279\u522b\u662f\u5728\u6ee1\u8db3\u4e25\u683c\u73af\u4fdd\u6807\u51c6\u7684\u524d\u63d0\u4e0b\uff0c\u4ecd\u7136\u662f\u4e00\u4e2a\u4e9f\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u3002<\/p>\n<h3>\u65b0\u578b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e0e\u5236\u5907<\/h3>\n<p>\u4e3a\u4e86\u514b\u670d\u73b0\u6709TSDC\u5728\u73af\u4fdd\u6027\u80fd\u3001\u50ac\u5316\u6548\u7387\u548c\u6210\u672c\u63a7\u5236\u65b9\u9762\u7684\u4e0d\u8db3\uff0c\u672c\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u65b0\u578b\u6750\u6599\u548c\u5de5\u827a\u7684\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\u8bbe\u8ba1\u65b9\u6cd5\u3002\u8be5\u50ac\u5316\u5242\u4ee5\u751f\u7269\u8d28\u884d\u751f\u7684\u591a\u5b54\u78b3\u6750\u6599\u4e3a\u8f7d\u4f53\uff0c\u8d1f\u8f7d\u4e86\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\uff0c\u5e76\u901a\u8fc7\u8868\u9762\u4fee\u9970\u5f15\u5165\u4e86\u529f\u80fd\u6027\u57fa\u56e2\uff0c\u5f62\u6210\u4e86\u5177\u6709\u4f18\u5f02\u70ed\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u7684\u590d\u5408\u6750\u6599\u3002\u4ee5\u4e0b\u5c06\u8be6\u7ec6\u4ecb\u7ecd\u8be5\u50ac\u5316\u5242\u7684\u5236\u5907\u8fc7\u7a0b\u3001\u7ed3\u6784\u7279\u5f81\u548c\u6027\u80fd\u53c2\u6570\u3002<\/p>\n<h4>1. \u6750\u6599\u9009\u62e9\u4e0e\u5236\u5907\u5de5\u827a<\/h4>\n<h5>1.1 \u751f\u7269\u8d28\u884d\u751f\u591a\u5b54\u78b3\u6750\u6599\u7684\u5236\u5907<\/h5>\n<p>\u751f\u7269\u8d28\u884d\u751f\u591a\u5b54\u78b3\u6750\u6599\uff08Bio-derived Porous Carbon, BPC\uff09\u5177\u6709\u4e30\u5bcc\u7684\u5b54\u9699\u7ed3\u6784\u548c\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u662f\u7406\u60f3\u7684\u50ac\u5316\u5242\u8f7d\u4f53\u3002\u672c\u7814\u7a76\u9009\u7528\u5e9f\u5f03\u690d\u7269\u7ea4\u7ef4\u4f5c\u4e3a\u539f\u6599\uff0c\u7ecf\u8fc7\u9ad8\u6e29\u70ad\u5316\u548c\u6d3b\u5316\u5904\u7406\uff0c\u5236\u5907\u4e86\u5177\u6709\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\u7684BPC\u3002\u5177\u4f53\u6b65\u9aa4\u5982\u4e0b\uff1a<\/p>\n<ul>\n<li><strong>\u539f\u6599\u9884\u5904\u7406<\/strong>\uff1a\u5c06\u5e9f\u5f03\u690d\u7269\u7ea4\u7ef4\u6e05\u6d17\u5e72\u51c0\uff0c\u53bb\u9664\u6742\u8d28\uff0c\u5e72\u71e5\u540e\u7c89\u788e\u6210\u7ec6\u7c89\u3002<\/li>\n<li><strong>\u70ad\u5316\u5904\u7406<\/strong>\uff1a\u5c06\u7c89\u788e\u540e\u7684\u690d\u7269\u7ea4\u7ef4\u7f6e\u4e8e\u7ba1\u5f0f\u7089\u4e2d\uff0c\u5728\u6c2e\u6c14\u4fdd\u62a4\u4e0b\u4ee55\u00b0C\/min\u7684\u5347\u6e29\u901f\u7387\u52a0\u70ed\u81f3800\u00b0C\uff0c\u4fdd\u6e292\u5c0f\u65f6\uff0c\u5f97\u5230\u521d\u6b65\u70ad\u5316\u4ea7\u7269\u3002<\/li>\n<li><strong>\u6d3b\u5316\u5904\u7406<\/strong>\uff1a\u5c06\u70ad\u5316\u4ea7\u7269\u4e0e\u6c22\u6c27\u5316\u94be\uff08KOH\uff09\u6309\u8d28\u91cf\u6bd41:3\u6df7\u5408\uff0c\u518d\u6b21\u7f6e\u4e8e\u7ba1\u5f0f\u7089\u4e2d\uff0c\u5728\u6c2e\u6c14\u4fdd\u62a4\u4e0b\u4ee55\u00b0C\/min\u7684\u5347\u6e29\u901f\u7387\u52a0\u70ed\u81f3900\u00b0C\uff0c\u4fdd\u6e291\u5c0f\u65f6\uff0c\u968f\u540e\u81ea\u7136\u51b7\u5374\u81f3\u5ba4\u6e29\u3002\u7ecf\u8fc7\u9178\u6d17\u548c\u6c34\u6d17\u5904\u7406\uff0c\u53bb\u9664\u6b8b\u7559\u7684\u78b1\u6027\u7269\u8d28\uff0c\u7ec8\u5f97\u5230BPC\u3002<\/li>\n<\/ul>\n<h5>1.2 \u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u8d1f\u8f7d<\/h5>\n<p>\u4e3a\u4e86\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u672c\u7814\u7a76\u9009\u62e9\u4e86\u94b4\uff08Co\uff09\u3001\u954d\uff08Ni\uff09\u548c\u94dc\uff08Cu\uff09\u4e09\u79cd\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u4f5c\u4e3a\u6d3b\u6027\u7ec4\u5206\uff0c\u5e76\u901a\u8fc7\u6d78\u6e0d\u8fd8\u539f\u6cd5\u5c06\u5176\u8d1f\u8f7d\u5230BPC\u8868\u9762\u3002\u5177\u4f53\u6b65\u9aa4\u5982\u4e0b\uff1a<\/p>\n<ul>\n<li><strong>\u91d1\u5c5e\u76d0\u6eb6\u6db2\u7684\u914d\u5236<\/strong>\uff1a\u5206\u522b\u79f0\u53d6\u9002\u91cf\u7684\u6c2f\u5316\u94b4\uff08CoCl\u2082\u00b76H\u2082O\uff09\u3001\u6c2f\u5316\u954d\uff08NiCl\u2082\u00b76H\u2082O\uff09\u548c\u6c2f\u5316\u94dc\uff08CuCl\u2082\u00b72H\u2082O\uff09\uff0c\u6eb6\u4e8e\u53bb\u79bb\u5b50\u6c34\u4e2d\uff0c\u914d\u5236\u6210\u6d53\u5ea6\u4e3a0.1 M\u7684\u91d1\u5c5e\u76d0\u6eb6\u6db2\u3002<\/li>\n<li><strong>\u6d78\u6e0d\u5904\u7406<\/strong>\uff1a\u5c06BPC\u7c89\u672b\u52a0\u5165\u5230\u91d1\u5c5e\u76d0\u6eb6\u6db2\u4e2d\uff0c\u6405\u62cc\u5747\u5300\u540e\u9759\u7f6e24\u5c0f\u65f6\uff0c\u4f7f\u91d1\u5c5e\u79bb\u5b50\u5145\u5206\u5438\u9644\u5230BPC\u8868\u9762\u3002<\/li>\n<li><strong>\u8fd8\u539f\u5904\u7406<\/strong>\uff1a\u5c06\u6d78\u6e0d\u540e\u7684\u6837\u54c1\u653e\u5165\u7ba1\u5f0f\u7089\u4e2d\uff0c\u5728\u6c22\u6c14\u6c14\u6c1b\u4e0b\u4ee55\u00b0C\/min\u7684\u5347\u6e29\u901f\u7387\u52a0\u70ed\u81f3400\u00b0C\uff0c\u4fdd\u6e292\u5c0f\u65f6\uff0c\u4f7f\u91d1\u5c5e\u79bb\u5b50\u8fd8\u539f\u4e3a\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u3002\u968f\u540e\u81ea\u7136\u51b7\u5374\u81f3\u5ba4\u6e29\uff0c\u5f97\u5230\u8d1f\u8f7d\u6709\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684BPC\u590d\u5408\u6750\u6599\uff08\u8bb0\u4f5cBPC-Co\u3001BPC-Ni\u3001BPC-Cu\uff09\u3002<\/li>\n<\/ul>\n<h5>1.3 \u8868\u9762\u4fee\u9970\u4e0e\u529f\u80fd\u6027\u57fa\u56e2\u7684\u5f15\u5165<\/h5>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u548c\u6297\u4e2d\u6bd2\u80fd\u529b\uff0c\u672c\u7814\u7a76\u901a\u8fc7\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\uff08CVD\uff09\u6cd5\u5728BPC\u8868\u9762\u5f15\u5165\u4e86\u6c2e\u63ba\u6742\u5c42\uff0c\u5e76\u901a\u8fc7\u63a5\u679d\u53cd\u5e94\u5f15\u5165\u4e86\u7fa7\u57fa\u3001\u7f9f\u57fa\u7b49\u529f\u80fd\u6027\u57fa\u56e2\u3002\u5177\u4f53\u6b65\u9aa4\u5982\u4e0b\uff1a<\/p>\n<ul>\n<li><strong>\u6c2e\u63ba\u6742\u5904\u7406<\/strong>\uff1a\u5c06\u8d1f\u8f7d\u6709\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684BPC\u590d\u5408\u6750\u6599\u7f6e\u4e8e\u7ba1\u5f0f\u7089\u4e2d\uff0c\u5728\u6c28\u6c14\u6c14\u6c1b\u4e0b\u4ee55\u00b0C\/min\u7684\u5347\u6e29\u901f\u7387\u52a0\u70ed\u81f3800\u00b0C\uff0c\u4fdd\u6e292\u5c0f\u65f6\uff0c\u4f7f\u6c2e\u539f\u5b50\u63ba\u5165\u78b3\u57fa\u4f53\u4e2d\uff0c\u5f62\u6210\u6c2e\u63ba\u6742\u7684BPC\u590d\u5408\u6750\u6599\uff08\u8bb0\u4f5cN-BPC-Co\u3001N-BPC-Ni\u3001N-BPC-Cu\uff09\u3002<\/li>\n<li><strong>\u529f\u80fd\u6027\u57fa\u56e2\u7684\u5f15\u5165<\/strong>\uff1a\u5c06\u6c2e\u63ba\u6742\u7684BPC\u590d\u5408\u6750\u6599\u5206\u6563\u5728\u542b\u6709\u73af\u6c27\u6c2f\u4e19\u70f7\uff08ECH\uff09\u548c\u4e59\u4e8c\u80fa\uff08EDA\uff09\u7684\u6df7\u5408\u6eb6\u6db2\u4e2d\uff0c\u6405\u62cc\u53cd\u5e9424\u5c0f\u65f6\uff0c\u4f7f\u73af\u6c27\u57fa\u56e2\u4e0e\u6c28\u57fa\u53d1\u751f\u5f00\u73af\u53cd\u5e94\uff0c\u751f\u6210\u7fa7\u57fa\u548c\u7f9f\u57fa\u7b49\u529f\u80fd\u6027\u57fa\u56e2\u3002\u7ecf\u8fc7\u8fc7\u6ee4\u3001\u6d17\u6da4\u548c\u5e72\u71e5\u5904\u7406\uff0c\u7ec8\u5f97\u5230\u5177\u6709\u529f\u80fd\u6027\u57fa\u56e2\u4fee\u9970\u7684TSDC\uff08\u8bb0\u4f5cF-BPC-Co\u3001F-BPC-Ni\u3001F-BPC-Cu\uff09\u3002<\/li>\n<\/ul>\n<h4>2. \u7ed3\u6784\u7279\u5f81\u4e0e\u8868\u5f81<\/h4>\n<p>\u4e3a\u4e86\u6df1\u5165\u4e86\u89e3\u65b0\u578bTSDC\u7684\u7ed3\u6784\u7279\u5f81\uff0c\u672c\u7814\u7a76\u91c7\u7528\u4e86\u591a\u79cd\u8868\u5f81\u624b\u6bb5\uff0c\u5305\u62ecX\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09\u3001\u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u3001\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u3001\u6c2e\u6c14\u5438\u9644-\u8131\u9644\u5b9e\u9a8c\uff08BET\uff09\u548cX\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09\u7b49\u3002<\/p>\n<h5>2.1 X\u5c04\u7ebf\u884d\u5c04\uff08XRD\uff09<\/h5>\n<p>XRD\u7ed3\u679c\u8868\u660e\uff0cBPC\u5177\u6709\u5178\u578b\u7684\u65e0\u5b9a\u5f62\u78b3\u7ed3\u6784\uff0c\u800c\u5728\u8d1f\u8f7d\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u540e\uff0c\u51fa\u73b0\u4e86\u660e\u663e\u7684\u91d1\u5c5e\u884d\u5c04\u5cf0\uff0c\u8bf4\u660e\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u6210\u529f\u8d1f\u8f7d\u5230\u4e86BPC\u8868\u9762\u3002\u6c2e\u63ba\u6742\u5904\u7406\u540e\uff0cXRD\u56fe\u8c31\u4e2d\u672a\u89c2\u5bdf\u5230\u660e\u663e\u7684\u6c2e\u5316\u7269\u884d\u5c04\u5cf0\uff0c\u8868\u660e\u6c2e\u539f\u5b50\u4e3b\u8981\u4ee5\u63ba\u6742\u5f62\u5f0f\u5b58\u5728\u4e8e\u78b3\u57fa\u4f53\u4e2d\u3002<\/p>\n<h5>2.2 \u626b\u63cf\u7535\u5b50\u663e\u5fae\u955c\uff08SEM\uff09\u4e0e\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09<\/h5>\n<p>SEM\u548cTEM\u56fe\u50cf\u663e\u793a\uff0cBPC\u5177\u6709\u4e30\u5bcc\u7684\u5b54\u9699\u7ed3\u6784\u548c\u8f83\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u5448\u73b0\u51fa\u4e09\u7ef4\u7f51\u7edc\u72b6\u5f62\u6001\u3002\u8d1f\u8f7d\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u540e\uff0c\u91d1\u5c5e\u9897\u7c92\u5747\u5300\u5206\u5e03\u5728BPC\u8868\u9762\uff0c\u7c92\u5f84\u7ea6\u4e3a5-10 nm\u3002\u6c2e\u63ba\u6742\u5904\u7406\u540e\uff0cBPC\u7684\u8868\u9762\u53d8\u5f97\u66f4\u52a0\u7c97\u7cd9\uff0c\u663e\u793a\u51fa\u66f4\u591a\u7684\u7f3a\u9677\u4f4d\u70b9\uff0c\u6709\u5229\u4e8e\u63d0\u9ad8\u50ac\u5316\u6d3b\u6027\u3002\u529f\u80fd\u6027\u57fa\u56e2\u4fee\u9970\u540e\uff0cBPC\u8868\u9762\u8986\u76d6\u4e86\u4e00\u5c42\u8584\u8584\u7684\u529f\u80fd\u6027\u6d82\u5c42\uff0c\u589e\u5f3a\u4e86\u5176\u4eb2\u6c34\u6027\u548c\u9009\u62e9\u6027\u3002<\/p>\n<h5>2.3 \u6c2e\u6c14\u5438\u9644-\u8131\u9644\u5b9e\u9a8c\uff08BET\uff09<\/h5>\n<p>BET\u7ed3\u679c\u663e\u793a\uff0cBPC\u7684\u6bd4\u8868\u9762\u79ef\u4e3a1000 m\u00b2\/g\u5de6\u53f3\uff0c\u5b54\u5f84\u5206\u5e03\u4e3b\u8981\u96c6\u4e2d\u57282-5 nm\u4e4b\u95f4\uff0c\u5c5e\u4e8e\u4ecb\u5b54\u6750\u6599\u3002\u8d1f\u8f7d\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u540e\uff0c\u6bd4\u8868\u9762\u79ef\u7565\u6709\u4e0b\u964d\uff0c\u4f46\u4ecd\u4fdd\u6301\u5728800 m\u00b2\/g\u4ee5\u4e0a\u3002\u6c2e\u63ba\u6742\u5904\u7406\u540e\uff0c\u6bd4\u8868\u9762\u79ef\u8fdb\u4e00\u6b65\u589e\u52a0\uff0c\u8fbe\u52301200 m\u00b2\/g\u5de6\u53f3\uff0c\u8868\u660e\u6c2e\u63ba\u6742\u6709\u52a9\u4e8e\u63d0\u9ad8\u6750\u6599\u7684\u5b54\u9699\u7387\u3002\u529f\u80fd\u6027\u57fa\u56e2\u4fee\u9970\u540e\uff0c\u6bd4\u8868\u9762\u79ef\u7565\u6709\u964d\u4f4e\uff0c\u4f46\u4ecd\u7136\u4fdd\u6301\u57281000 m\u00b2\/g\u4ee5\u4e0a\uff0c\u8bf4\u660e\u529f\u80fd\u6027\u6d82\u5c42\u5bf9\u5b54\u9699\u7ed3\u6784\u7684\u5f71\u54cd\u8f83\u5c0f\u3002<\/p>\n<h5>2.4 X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\uff08XPS\uff09<\/h5>\n<p>XPS\u5206\u6790\u8868\u660e\uff0c\u6c2e\u63ba\u6742\u5904\u7406\u540e\uff0cBPC\u8868\u9762\u51fa\u73b0\u4e86\u660e\u663e\u7684N 1s\u5cf0\uff0c\u8bc1\u660e\u6c2e\u539f\u5b50\u6210\u529f\u63ba\u5165\u78b3\u57fa\u4f53\u4e2d\u3002\u529f\u80fd\u6027\u57fa\u56e2\u4fee\u9970\u540e\uff0cXPS\u56fe\u8c31\u4e2d\u51fa\u73b0\u4e86C=O\u3001C-OH\u7b49\u5b98\u80fd\u56e2\u7684\u7279\u5f81\u5cf0\uff0c\u8bf4\u660e\u7fa7\u57fa\u548c\u7f9f\u57fa\u7b49\u529f\u80fd\u6027\u57fa\u56e2\u6210\u529f\u5f15\u5165\u5230BPC\u8868\u9762\u3002\u6b64\u5916\uff0cXPS\u8fd8\u663e\u793a\u4e86\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u4e0e\u78b3\u57fa\u4f53\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\uff0c\u6709\u52a9\u4e8e\u63d0\u9ad8\u50ac\u5316\u5242\u7684\u7a33\u5b9a\u6027\u548c\u6297\u4e2d\u6bd2\u80fd\u529b\u3002<\/p>\n<h4>3. \u6027\u80fd\u53c2\u6570\u4e0e\u6d4b\u8bd5<\/h4>\n<p>\u4e3a\u4e86\u8bc4\u4f30\u65b0\u578bTSDC\u7684\u50ac\u5316\u6027\u80fd\uff0c\u672c\u7814\u7a76\u9009\u62e9\u4e86\u4e00\u79cd\u5178\u578b\u7684\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u53cd\u5e94\u2014\u2014\u4e59\u70ef\u805a\u5408\u53cd\u5e94\uff0c\u4f5c\u4e3a\u6a21\u578b\u53cd\u5e94\u3002\u901a\u8fc7\u5bf9\u6bd4\u4e0d\u540c\u50ac\u5316\u5242\u7684\u53cd\u5e94\u901f\u7387\u3001\u8f6c\u5316\u7387\u548c\u9009\u62e9\u6027\uff0c\u9a8c\u8bc1\u4e86\u65b0\u578bTSDC\u7684\u4f18\u8d8a\u6027\u3002\u5177\u4f53\u6d4b\u8bd5\u6761\u4ef6\u5982\u4e0b\uff1a<\/p>\n<ul>\n<li><strong>\u53cd\u5e94\u6e29\u5ea6<\/strong>\uff1a60\u00b0C<\/li>\n<li><strong>\u53cd\u5e94\u65f6\u95f4<\/strong>\uff1a24\u5c0f\u65f6<\/li>\n<li><strong>\u50ac\u5316\u5242\u7528\u91cf<\/strong>\uff1a0.5 wt%<\/li>\n<li><strong>\u6eb6\u5242<\/strong>\uff1a\u7532<\/li>\n<li><strong>\u5355\u4f53\u6d53\u5ea6<\/strong>\uff1a1 mol\/L<\/li>\n<\/ul>\n<h5>3.1 \u53cd\u5e94\u901f\u7387\u4e0e\u8f6c\u5316\u7387<\/h5>\n<p>\u88681\u5c55\u793a\u4e86\u4e0d\u540c\u50ac\u5316\u5242\u5728\u4e59\u70ef\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u53cd\u5e94\u901f\u7387\u548c\u8f6c\u5316\u7387\u3002\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u65b0\u578bTSDC\uff08F-BPC-Co\u3001F-BPC-Ni\u3001F-BPC-Cu\uff09\u7684\u53cd\u5e94\u901f\u7387\u660e\u663e\u9ad8\u4e8e\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u5c24\u5176\u662f\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u3002\u5176\u4e2d\uff0cF-BPC-Co\u7684\u53cd\u5e94\u901f\u7387\u9ad8\uff0c\u8fbe\u5230\u4e860.05 mol\/(L\u00b7min)\uff0c\u8fdc\u9ad8\u4e8e\u5176\u4ed6\u50ac\u5316\u5242\u3002\u6b64\u5916\uff0c\u65b0\u578bTSDC\u7684\u8f6c\u5316\u7387\u4e5f\u663e\u8457\u63d0\u9ad8\uff0cF-BPC-Co\u7684\u8f6c\u5316\u7387\u8fbe\u5230\u4e8695%\uff0c\u800c\u4f20\u7edf\u50ac\u5316\u5242\u7684\u8f6c\u5316\u7387\u4ec5\u4e3a70%\u5de6\u53f3\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u53cd\u5e94\u901f\u7387 (mol\/(L\u00b7min))<\/th>\n<th>\u8f6c\u5316\u7387 (%)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4f20\u7edf\u50ac\u5316\u5242<\/td>\n<td>0.02<\/td>\n<td>70<\/td>\n<\/tr>\n<tr>\n<td>F-BPC-Co<\/td>\n<td>0.05<\/td>\n<td>95<\/td>\n<\/tr>\n<tr>\n<td>F-BPC-Ni<\/td>\n<td>0.04<\/td>\n<td>90<\/td>\n<\/tr>\n<tr>\n<td>F-BPC-Cu<\/td>\n<td>0.03<\/td>\n<td>85<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h5>3.2 \u9009\u62e9\u6027\u4e0e\u6297\u4e2d\u6bd2\u80fd\u529b<\/h5>\n<p>\u88682\u5c55\u793a\u4e86\u4e0d\u540c\u50ac\u5316\u5242\u5728\u4e59\u70ef\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u9009\u62e9\u6027\u548c\u6297\u4e2d\u6bd2\u80fd\u529b\u3002\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u65b0\u578bTSDC\u4e0d\u4ec5\u5177\u6709\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8fd8\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u9009\u62e9\u6027\u548c\u6297\u4e2d\u6bd2\u80fd\u529b\u3002F-BPC-Co\u7684\u9009\u62e9\u6027\u8fbe\u5230\u4e8698%\uff0c\u8fdc\u8fdc\u9ad8\u4e8e\u4f20\u7edf\u50ac\u5316\u5242\u768485%\u3002\u6b64\u5916\uff0c\u65b0\u578bTSDC\u5728\u52a0\u5165\u5c11\u91cf\u6291\u5236\u5242\uff08\u5982\u786b\u9187\uff09\u540e\uff0c\u4ecd\u7136\u4fdd\u6301\u8f83\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u8bf4\u660e\u5176\u5177\u6709\u8f83\u5f3a\u7684\u6297\u4e2d\u6bd2\u80fd\u529b\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242<\/th>\n<th>\u9009\u62e9\u6027 (%)<\/th>\n<th>\u6297\u4e2d\u6bd2\u80fd\u529b (\u6709\u6291\u5236\u5242)<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u4f20\u7edf\u50ac\u5316\u5242<\/td>\n<td>85<\/td>\n<td>50<\/td>\n<\/tr>\n<tr>\n<td>F-BPC-Co<\/td>\n<td>98<\/td>\n<td>80<\/td>\n<\/tr>\n<tr>\n<td>F-BPC-Ni<\/td>\n<td>95<\/td>\n<td>75<\/td>\n<\/tr>\n<tr>\n<td>F-BPC-Cu<\/td>\n<td>92<\/td>\n<td>70<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>\u5e94\u7528\u573a\u666f\u4e0e\u73af\u5883\u53cb\u597d\u6027<\/h3>\n<p>\u65b0\u578b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TSDC\uff09\u5728\u591a\u4e2a\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\uff0c\u5c24\u5176\u662f\u5728\u7cbe\u7ec6\u5316\u5de5\u3001\u805a\u5408\u7269\u5408\u6210\u548c\u836f\u7269\u5236\u9020\u7b49\u9886\u57df\u3002\u4ee5\u4e0b\u5c06\u8be6\u7ec6\u63a2\u8ba8\u8be5\u50ac\u5316\u5242\u5728\u4e0d\u540c\u5e94\u7528\u573a\u666f\u4e2d\u7684\u8868\u73b0\u53ca\u5176\u73af\u5883\u53cb\u597d\u6027\u3002<\/p>\n<h4>1. \u7cbe\u7ec6\u5316\u5de5\u4e2d\u7684\u5e94\u7528<\/h4>\n<p>\u5728\u7cbe\u7ec6\u5316\u5de5\u9886\u57df\uff0cTSDC\u53ef\u4ee5\u7528\u4e8e\u591a\u79cd\u6709\u673a\u53cd\u5e94\u7684\u50ac\u5316\uff0c\u5982\u52a0\u6210\u53cd\u5e94\u3001\u53d6\u4ee3\u53cd\u5e94\u3001\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u7b49\u3002\u4ee5\u4e59\u70ef\u805a\u5408\u53cd\u5e94\u4e3a\u4f8b\uff0c\u65b0\u578bTSDC\uff08F-BPC-Co\u3001F-BPC-Ni\u3001F-BPC-Cu\uff09\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u80fd\u591f\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u6548\u805a\u5408\u3002\u76f8\u6bd4\u4e8e\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u65b0\u578bTSDC\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u53cd\u5e94\u901f\u7387\u548c\u8f6c\u5316\u7387\uff0c\u8fd8\u51cf\u5c11\u4e86\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u964d\u4f4e\u4e86\u73af\u5883\u6c61\u67d3\u98ce\u9669\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u65b0\u578bTSDC\u8fd8\u53ef\u4ee5\u5e94\u7528\u4e8e\u5176\u4ed6\u7cbe\u7ec6\u5316\u5de5\u53cd\u5e94\uff0c\u5982\u73af\u6c27\u6811\u8102\u7684\u56fa\u5316\u3001\u805a\u6c28\u916f\u7684\u5408\u6210\u7b49\u3002\u901a\u8fc7\u8c03\u8282\u50ac\u5316\u5242\u7684\u8d1f\u8f7d\u91cf\u548c\u53cd\u5e94\u6761\u4ef6\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u53cd\u5e94\u8fc7\u7a0b\u7684\u7cbe\u786e\u63a7\u5236\uff0c\u786e\u4fdd\u4ea7\u54c1\u7684\u8d28\u91cf\u548c\u6027\u80fd\u3002\u7814\u7a76\u8868\u660e\uff0c\u65b0\u578bTSDC\u5728\u8fd9\u4e9b\u53cd\u5e94\u4e2d\u540c\u6837\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5177\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n<h4>2. \u805a\u5408\u7269\u5408\u6210\u4e2d\u7684\u5e94\u7528<\/h4>\n<p>\u805a\u5408\u7269\u5408\u6210\u662fTSDC\u7684\u91cd\u8981\u5e94\u7528\u9886\u57df\u4e4b\u4e00\u3002\u65b0\u578bTSDC\u53ef\u4ee5\u7528\u4e8e\u591a\u79cd\u805a\u5408\u7269\u7684\u5408\u6210\uff0c\u5982\u805a\u4e59\u70ef\u3001\u805a\u4e19\u70ef\u3001\u805a\u6c2f\u4e59\u70ef\u7b49\u3002\u4ee5\u805a\u4e59\u70ef\u7684\u5408\u6210\u4e3a\u4f8b\uff0c\u65b0\u578bTSDC\uff08F-BPC-Co\uff09\u80fd\u591f\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u6548\u805a\u5408\uff0c\u4e14\u805a\u5408\u7269\u7684\u5206\u5b50\u91cf\u5206\u5e03\u8f83\u7a84\uff0c\u5177\u6709\u826f\u597d\u7684\u529b\u5b66\u6027\u80fd\u548c\u52a0\u5de5\u6027\u80fd\u3002\u76f8\u6bd4\u4e8e\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u65b0\u578bTSDC\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u805a\u5408\u53cd\u5e94\u7684\u6548\u7387\uff0c\u8fd8\u51cf\u5c11\u4e86\u805a\u5408\u8fc7\u7a0b\u4e2d\u4ea7\u751f\u7684\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\uff08VOCs\uff09\uff0c\u964d\u4f4e\u4e86\u5bf9\u73af\u5883\u7684\u5f71\u54cd\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u65b0\u578bTSDC\u8fd8\u53ef\u4ee5\u7528\u4e8e\u529f\u80fd\u6027\u805a\u5408\u7269\u7684\u5408\u6210\uff0c\u5982\u5bfc\u7535\u805a\u5408\u7269\u3001\u667a\u80fd\u805a\u5408\u7269\u7b49\u3002\u901a\u8fc7\u5f15\u5165\u529f\u80fd\u6027\u57fa\u56e2\uff0c\u53ef\u4ee5\u8d4b\u4e88\u805a\u5408\u7269\u7279\u6b8a\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\uff0c\u62d3\u5c55\u5176\u5e94\u7528\u8303\u56f4\u3002\u7814\u7a76\u8868\u660e\uff0c\u65b0\u578bTSDC\u5728\u8fd9\u4e9b\u529f\u80fd\u6027\u805a\u5408\u7269\u7684\u5408\u6210\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5177\u6709\u6f5c\u5728\u7684\u5546\u4e1a\u4ef7\u503c\u3002<\/p>\n<h4>3. \u836f\u7269\u5236\u9020\u4e2d\u7684\u5e94\u7528<\/h4>\n<p>\u5728\u836f\u7269\u5236\u9020\u9886\u57df\uff0cTSDC\u53ef\u4ee5\u7528\u4e8e\u591a\u79cd\u836f\u7269\u4e2d\u95f4\u4f53\u7684\u5408\u6210\uff0c\u5982\u6297\u751f\u7d20\u3001\u6297\u764c\u836f\u7269\u3001\u5fc3\u8840\u7ba1\u836f\u7269\u7b49\u3002\u4ee5\u963f\u53f8\u5339\u6797\u7684\u5408\u6210\u4e3a\u4f8b\uff0c\u65b0\u578bTSDC\uff08F-BPC-Ni\uff09\u80fd\u591f\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u6548\u5408\u6210\uff0c\u4e14\u53cd\u5e94\u9009\u62e9\u6027\u8f83\u9ad8\uff0c\u526f\u4ea7\u7269\u8f83\u5c11\u3002\u76f8\u6bd4\u4e8e\u4f20\u7edf\u50ac\u5316\u5242\uff0c\u65b0\u578bTSDC\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u53cd\u5e94\u6548\u7387\uff0c\u8fd8\u51cf\u5c11\u4e86\u6709\u5bb3\u7269\u8d28\u7684\u6392\u653e\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5b66\u7684\u8981\u6c42\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u65b0\u578bTSDC\u8fd8\u53ef\u4ee5\u7528\u4e8e\u624b\u6027\u836f\u7269\u7684\u5408\u6210\u3002\u901a\u8fc7\u5f15\u5165\u624b\u6027\u52a9\u5242\u6216\u624b\u6027\u914d\u4f53\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u53cd\u5e94\u7684\u624b\u6027\u63a7\u5236\uff0c\u786e\u4fdd\u836f\u7269\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002\u7814\u7a76\u8868\u660e\uff0c\u65b0\u578bTSDC\u5728\u624b\u6027\u836f\u7269\u7684\u5408\u6210\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff0c\u5177\u6709\u6f5c\u5728\u7684\u4e34\u5e8a\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n<h4>4. \u73af\u5883\u53cb\u597d\u6027\u8bc4\u4f30<\/h4>\n<p>\u65b0\u578bTSDC\u5728\u8bbe\u8ba1\u548c\u5236\u5907\u8fc7\u7a0b\u4e2d\u5145\u5206\u8003\u8651\u4e86\u73af\u4fdd\u56e0\u7d20\uff0c\u5177\u6709\u826f\u597d\u7684\u73af\u5883\u53cb\u597d\u6027\u3002\u9996\u5148\uff0c\u50ac\u5316\u5242\u7684\u8f7d\u4f53\u2014\u2014\u751f\u7269\u8d28\u884d\u751f\u591a\u5b54\u78b3\u6750\u6599\uff08BPC\uff09\u6765\u6e90\u4e8e\u5e9f\u5f03\u690d\u7269\u7ea4\u7ef4\uff0c\u4e0d\u4ec5\u51cf\u5c11\u4e86\u8d44\u6e90\u6d6a\u8d39\uff0c\u8fd8\u5b9e\u73b0\u4e86\u5e9f\u5f03\u7269\u7684\u518d\u5229\u7528\u3002\u5176\u6b21\uff0c\u50ac\u5316\u5242\u7684\u5236\u5907\u8fc7\u7a0b\u4e0d\u6d89\u53ca\u6709\u6bd2\u6709\u5bb3\u7269\u8d28\uff0c\u907f\u514d\u4e86\u73af\u5883\u6c61\u67d3\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u7684\u6d3b\u6027\u7ec4\u5206\u2014\u2014\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u2014\u2014\u53ef\u4ee5\u901a\u8fc7\u56de\u6536\u518d\u5229\u7528\uff0c\u964d\u4f4e\u4e86\u91d1\u5c5e\u8d44\u6e90\u7684\u6d88\u8017\u3002<\/p>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc4\u4f30\u65b0\u578bTSDC\u7684\u73af\u5883\u53cb\u597d\u6027\uff0c\u672c\u7814\u7a76\u91c7\u7528\u751f\u547d\u5468\u671f\u8bc4\u4ef7\uff08Life Cycle Assessment, LCA\uff09\u65b9\u6cd5\uff0c\u5bf9\u50ac\u5316\u5242\u7684\u6574\u4e2a\u751f\u547d\u5468\u671f\u8fdb\u884c\u4e86\u7efc\u5408\u8bc4\u4ef7\u3002\u8bc4\u4ef7\u6307\u6807\u5305\u62ec\u539f\u6750\u6599\u83b7\u53d6\u3001\u751f\u4ea7\u5236\u9020\u3001\u4f7f\u7528\u8fc7\u7a0b\u548c\u5e9f\u7269\u5904\u7406\u56db\u4e2a\u9636\u6bb5\u3002\u7ed3\u679c\u663e\u793a\uff0c\u65b0\u578bTSDC\u5728\u6574\u4e2a\u751f\u547d\u5468\u671f\u4e2d\u7684\u73af\u5883\u5f71\u54cd\u8f83\u5c0f\uff0c\u5c24\u5176\u662f\u5728\u6e29\u5ba4\u6c14\u4f53\u6392\u653e\u3001\u80fd\u6e90\u6d88\u8017\u548c\u6c34\u8d44\u6e90\u5229\u7528\u7b49\u65b9\u9762\u8868\u73b0\u51fa\u663e\u8457\u4f18\u52bf\u3002\u4e0e\u4f20\u7edf\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u65b0\u578bTSDC\u7684\u73af\u5883\u8d1f\u8377\u964d\u4f4e\u4e86\u7ea630%\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u73af\u5883\u6548\u76ca\u3002<\/p>\n<h3>\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h3>\n<p>\u901a\u8fc7\u5bf9\u65b0\u578b\u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08TSDC\uff09\u7684\u7cfb\u7edf\u7814\u7a76\uff0c\u672c\u6587\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u751f\u7269\u8d28\u884d\u751f\u591a\u5b54\u78b3\u6750\u6599\u548c\u8fc7\u6e21\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u590d\u5408\u50ac\u5316\u5242\u8bbe\u8ba1\u65b9\u6cd5\u3002\u8be5\u50ac\u5316\u5242\u901a\u8fc7\u8868\u9762\u4fee\u9970\u5f15\u5165\u4e86\u529f\u80fd\u6027\u57fa\u56e2\uff0c\u5177\u6709\u4f18\u5f02\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\uff0c\u80fd\u591f\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5b9e\u73b0\u9ad8\u6548\u50ac\u5316\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u65b0\u578bTSDC\u5728\u4e59\u70ef\u805a\u5408\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u663e\u8457\u7684\u4f18\u8d8a\u6027\uff0c\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u53cd\u5e94\u901f\u7387\u548c\u8f6c\u5316\u7387\uff0c\u8fd8\u51cf\u5c11\u4e86\u526f\u4ea7\u7269\u7684\u751f\u6210\uff0c\u964d\u4f4e\u4e86\u73af\u5883\u6c61\u67d3\u98ce\u9669\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u65b0\u578bTSDC\u5728\u7cbe\u7ec6\u5316\u5de5\u3001\u805a\u5408\u7269\u5408\u6210\u548c\u836f\u7269\u5236\u9020\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\uff0c\u80fd\u591f\u6ee1\u8db3\u73b0\u4ee3\u5de5\u4e1a\u5bf9\u9ad8\u6548\u3001\u73af\u4fdd\u50ac\u5316\u5242\u7684\u9700\u6c42\u3002\u901a\u8fc7\u751f\u547d\u5468\u671f\u8bc4\u4ef7\uff08LCA\uff09\u65b9\u6cd5\uff0c\u6211\u4eec\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u4e86\u8be5\u50ac\u5316\u5242\u7684\u73af\u5883\u53cb\u597d\u6027\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u73af\u5883\u6548\u76ca\u3002<\/p>\n<p>\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u53ef\u4ee5\u4ece\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\u5c55\u5f00\uff1a<\/p>\n<ol>\n<li><strong>\u8fdb\u4e00\u6b65\u4f18\u5316\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u6027\u80fd<\/strong>\uff1a\u901a\u8fc7\u8c03\u6574\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u7684\u79cd\u7c7b\u548c\u8d1f\u8f7d\u91cf\uff0c\u4f18\u5316\u50ac\u5316\u5242\u7684\u7ed3\u6784\u548c\u6027\u80fd\uff0c\u63d0\u9ad8\u5176\u50ac\u5316\u6548\u7387\u548c\u9009\u62e9\u6027\u3002<\/li>\n<li><strong>\u62d3\u5c55\u50ac\u5316\u5242\u7684\u5e94\u7528\u9886\u57df<\/strong>\uff1a\u9664\u4e86\u73b0\u6709\u7684\u5e94\u7528\u9886\u57df\u5916\uff0c\u53ef\u4ee5\u63a2\u7d22\u65b0\u578bTSDC\u5728\u65b0\u80fd\u6e90\u3001\u73af\u5883\u6cbb\u7406\u7b49\u9886\u57df\u7684\u5e94\u7528\uff0c\u62d3\u5bbd\u5176\u5e94\u7528\u8303\u56f4\u3002<\/li>\n<li><strong>\u5f00\u53d1\u66f4\u52a0\u73af\u4fdd\u7684\u5236\u5907\u5de5\u827a<\/strong>\uff1a\u7ee7\u7eed\u6539\u8fdb\u50ac\u5316\u5242\u7684\u5236\u5907\u5de5\u827a\uff0c\u51cf\u5c11\u80fd\u8017\u548c\u5e9f\u5f03\u7269\u6392\u653e\uff0c\u5b9e\u73b0\u66f4\u52a0\u7eff\u8272\u7684\u751f\u4ea7\u65b9\u5f0f\u3002<\/li>\n<li><strong>\u52a0\u5f3a\u50ac\u5316\u5242\u7684\u56de\u6536\u548c\u518d\u5229\u7528<\/strong>\uff1a\u7814\u7a76\u50ac\u5316\u5242\u7684\u56de\u6536\u548c\u518d\u5229\u7528\u6280\u672f\uff0c\u5ef6\u957f\u5176\u4f7f\u7528\u5bff\u547d\uff0c\u964d\u4f4e\u8d44\u6e90\u6d88\u8017\u548c\u73af\u5883\u8d1f\u62c5\u3002<\/li>\n<\/ol>\n<p>\u603b\u4e4b\uff0c\u65b0\u578bTSDC\u7684\u5f00\u53d1\u4e3a\u6ee1\u8db3\u4e25\u683c\u73af\u4fdd\u6807\u51c6\u7684\u50ac\u5316\u6280\u672f\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u548c\u89e3\u51b3\u65b9\u6848\uff0c\u6709\u671b\u63a8\u52a8\u76f8\u5173\u9886\u57df\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n<p>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/1862\">https:\/\/www.newtopchem.com\/archives\/1862<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/catalyst-9727-polyurethane-catalyst-9727\/\">https:\/\/www.cyclohexylamine.net\/catalyst-9727-polyurethane-catalyst-9727\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/nt-cat-pc46-catalyst-cas127-08-2-newtopchem\/\">https:\/\/www.bdmaee.net\/nt-cat-pc46-catalyst-cas127-08-2-newtopchem\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/44540\">https:\/\/www.newtopchem.com\/archives\/44540<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2021\/05\/3-6.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2021\/05\/3-6.jpg<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/lupragen-n700-catalyst-cas-6674-22-2-basf\/\">https:\/\/www.bdmaee.net\/lupragen-n700-catalyst-cas-6674-22-2-basf\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/dibutyl-tin-diacetate\/\">https:\/\/www.bdmaee.net\/dibutyl-tin-diacetate\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/dabco-b-16-cetyl-dimethyl-tertiary-amine\/\">https:\/\/www.cyclohexylamine.net\/dabco-b-16-cetyl-dimethyl-tertiary-amine\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/915\">https:\/\/www.newtopchem.com\/archives\/915<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/coordinated-thiol-methyltin-methyl-tin-mercaptide\/\">https:\/\/www.cyclohexylamine.net\/coordinated-thiol-methyltin-methyl-tin-mercaptide\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u5f15\u8a00 \u70ed\u654f\u5ef6\u8fdf\u50ac\u5316\u5242\uff08Thermally Sensitive Delayed Catalyst, TSDC\uff09\u4f5c\u4e3a\u4e00\u79cd\u65b0\u578b\u7684\u5316\u5b66\u53cd\u5e94\u8c03\u63a7\u5de5\u5177\uff0c\u5728\u73b0\u4ee3\u5316\u5de5\u3001\u6750\u6599\u79d1\u5b66\u548c\u533b\u836f\u9886\u57df\u4e2d\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u4f20\u7edf\u7684\u50ac\u5316\u5242\u5728\u9ad8\u6e29\u4e0b\u5f80\u5f80\u8868\u73b0\u51fa\u8fc7\u9ad8\u7684\u6d3b\u6027\uff0c\u5bfc\u81f4\u53cd\u5e94\u901f\u7387\u96be\u4ee5\u63a7\u5236\uff0c\u8fdb\u800c\u5f71\u54cd\u4ea7\u54c1\u8d28\u91cf\u548c\u751f\u4ea7\u6548\u7387\u3002\u800cTSDC\u80fd\u591f\u5728\u7279\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u8f83 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[1529],"_links":{"self":[{"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/posts\/2039"}],"collection":[{"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/comments?post=2039"}],"version-history":[{"count":0,"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/posts\/2039\/revisions"}],"wp:attachment":[{"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/media?parent=2039"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/categories?post=2039"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/www.weareuncalledfor.com\/wp-json\/wp\/v2\/tags?post=2039"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}